[Dioxin-l] Nature and halogens
Ronald Shore
ronaldshore@hotmail.com
Mon, 31 Jan 2000 17:23:48 PST
Some time back there was some discussion of naturally occurring
halogen-containing organic compounds, and then the topic seemed to fade
away.
I may have missed mention of it, so excuse any duplication. But there is a
paper in Nature (v.403, p. 292) describing coastal salt marshes as
significant sources of methyl chloride and bromide. This account adds
support to the view by some of those who have contributed to the list (but
seem to have been shouted down) that naturally occurring haloorganic
materials are not absent in our environment, but rather have been present
for a long time. It is too the case that through naturally occurring high
energy events (eg volcanoes, fires, lightning) and other chemistry
(atmospheric oxidants, mineral surfaces) they can be converted to a range of
other substances, most of them benign, but some long lasting and toxic.
Now it is clear that dioxins and related materials are toxic, and that they
are produced through the combustion of waste. Accordingly suitable waste
treatments must be developed, and treatments must be overseen by the proper
bodies.
But it must be recognized that nature produced these materials long before
we did, and always will. The elimination of chloroorganics forever, as some
have suggested, seems to be an extreme and probably futile route to take.
(I have absolutely no connection to any organization dealing with halogens
or waste treatment.)
RS
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