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Re: Background Dioxin Levels?



   If you wish, I believe my software will allow me to convert excell spread
  sheets to html coded web pages, if so I will set up a page on my site where
  they can be viewed online or downloaded as a saved web page. Jusyt send them
  to me as attached email I can open excel sheets in my computer convert them
  and publish to my site. I will then post to the list with an address where
  they can be viewed.
  
  RAymond Mills
  
  Tradeshows Online
  Developer of the Envirotrade 97 Environmental Tradeshow Online
  Voice: 406-295-1316  Voice Mail and Fax: 404-685-0842
  http://tradeshows-online.com  mailto:rmills@tradeshows-online.com
  
  -----Original Message-----
  From: Vivien Mountford <vivmount@greener.u-net.com>
  To: Multiple recipients of list <dioxin-l@essential.org>
  Date: Tuesday, August 26, 1997 4:01 PM
  Subject: RE: Background Dioxin Levels?
  
  
  
  >--=====================_872660083==_
  >Content-Type: text/plain; charset="us-ascii"
  >
  >Are Dennis's values in TEQ or not?  I assume not.
  >
  >Lets see if this message gets through (On August 17, I tried to send some
  >spreadsheets of dioxins in UK cowsmilk from near industrial sources.  That
  >message was rejected by the dioxin list server as being too big - if anyone
  >is still interested in cowsmilk sampling, please  let me know and I'll make
  >time to split it down into smaller chunks).
  >
  >I attach Excel spreadsheet data from the 1995 UK report by H.M.
  Inspectorate
  >of Pollution (HMIP) on dioxin in UK soils. [1]
  >Our computer is virus-checked every time it is powered on, so the attached
  >file should be safe to use.
  >
  >This small subset of samples from survey of UK soil samples gives mean TEQ
  >values
  >Urban locations (Mean of 5 samples) = total I-TEQ 28.37 ng/kg  (=ppt)
  >Rural locations (Mean of 11 samples) = total I-TEQ 5.17 ng/kg (=ppt)
  >The TEQ value for individual congeners are given in the spreadsheet.
  >
  >N.B.  Alan Watson says the data in that report is not very representative
  of
  >background dioxin levels in UK soil. He says that when he has time, he will
  >find and send out some better data.
  >
  >If you cannot read the spreadsheets and want the data instream, let me
  know.
  >
  >As you see, this is much higher than the 2 ppt under discussion, but it is
  >total TEQ per sample.  This report  analyses most of the samples by total
  >tetra- to octa- PCDDs and PCDFs, reanalysing relatively few samples into
  TEQ
  >values.   They gave a statistical summary of the full urban data set of 28
  >samples, which showed
  >
  > full urban data set of 28 samples      Report [1]
  >               mean ppt    median ppt
  >TCDD               70               60
  >PeCDD             80               70
  >HxCDD           170             180
  >HpCDD           640             280
  >OCDD            5500            740
  >
  >They didn't give a statistical summary of the rural samples, which is a
  pity
  >as they would better represent "background" presumably.
  >
  >It is interesting that in HMIP's earlier report [3] they give a summary for
  >a data set of 66 samples from a 50km grid across the UK (reduced from 78
  >samples by ignoring samples with value for any congener outside 2.5 std
  >deviations of the mean).  This would be more like background:
  >
  >Reduced data set of 66 UK soil samples (concentrations in ng/kg)   Report
  >[3] 1989
  >                        mean ppt    median ppt
  >TCDD                       9.4             6.0
  >2,3,7,8-TCDD        <0.5           <0.5
  >PeCDD                     6.6             4.6
  >1,2,3,7,8-PeCDD   <0.5          <0.5
  >HxCDD                    38              31
  >HpCDD                    66              55
  >OCDD                    190            140
  >
  >I wonder if Dennis is quoting median values, rather than mean values, as
  the
  >median values above match the means he quotes,  from work I suspect is from
  >the same co-author in the same year of 1989. I personally never got a grip
  >of the difference between mean and median, (lies, damn lies and statistics
  >if you ask me), but there does seem to be a difference in practise, as
  above.
  >
  >
  >The original 2ppt figure (quoted by Rebecca's FDA person) =  the same
  amount
  >as was estimated by a Dutch government committee (in 1996) to be the
  average
  >dioxin intake of the Dutch population  [2], so I wonder if Rebecca's FDA
  >person was really talking about background level in food, after all.
  >
  >The Dutch report said (p14) "Most adults in the Netherlands are exposed to
  >approximately 2 picogrammes of toxic equivalents of dioxin-like substances
  >per kilogramme of bodyweight per day."   This committee derived, from
  animal
  >studies, a health-based exposure limit of 1 picogramme TEQ/kg
  >bodyweight/day, which they recommended instead of the WHO limit of 10 pg
  >TEQ/kg bw/day.  As the Dutch population generally is exposed to twice their
  >recommended safe level, the committee concluded that the best way to limit
  >adults and babies intake to a safe level would be to reduce the exposure of
  >the whole population.  I do not know whether the Dutch government has
  >accepted these recommendations.
  >
  >[1] "Determination of polychlorinated biphenols, polychlorinated
  >dibenzo-p-dioxins and polychlorinated dibenzofurans in UK soils. 2nd
  >Technical Report" by E.A.Cox & C.S.Creaser.  Published by the then UK
  >regulators, H.M. Inspectorate of Pollution, December 1995.  I ASSUME that
  >the report is available from the UK Environment Agency, Rio House,
  Waterside
  >Drive, Aztec West, Almondsbury, Bristol, BS12 4UD, England, since HMIP
  >merged to become part of this Agency.
  >
  >[2] "Dioxins. Polychlorinated dibenzo-p-dioxins, dibenzofurans and
  >dioxin-like polychlorinated biphenols"  Health Council of the Netherlands:
  >Committee on Risk Evaluation of Substances/Dioxins.  Rijswijk: Health
  >Council of the Netherlands, 1996; Publication no. 1996/10E
  >
  >[3]  "Determination of polychlorinated biphenols, polychlorinated
  >dibenzo-p-dioxins and polychlorinated dibenzofurans in UK soils."  H.M.
  >Inspectorate of Pollution, 1989.
  >
  >Viv Mountford
  >
  >At 12:16 26/08/97 -0400, Catalano, Dennis wrote:
  >>This 2 -3 ppt range is a bit low actually from some references I have
  >>seen.  A study of soils in the UK had mean values of background of 6ppt
  >>for TCDD up to 143ppt for OCDD.  The furans ranged from 16ppt for TCDF
  >>to 32 ppt for HxCDF.  This data can be found in:
  >>
  >>Survey of Background Levels of PCDDs & PCDFs in UK Soils, Chemosphere,
  >>Vol 18 Nos 1-6  pp 767-776 1989.
  >>
  >>Some papers I have read find similar levels in the US.  I am sorry, but
  >>I do not have references to those at my fingertips.
  >>
  >>Dennis Catalano
  >> ----------
  >From: Rebecca Leighton Katers
  >To: Multiple recipients of list
  >Subject: Background Dioxin Levels?
  >Date: Tuesday, August 26, 1997 8:11AM
  >
  >I was just told by an FDA policy person that
  >recent information shows that dioxin background
  >levels range from 2 to 3 ppt.
  >
  >This seemed awfully high to me, so I questioned
  >him and asked if he meant background
  >in the food supply or natural background in the
  >soil --- and he said natural background in soil.
  >
  >He said that the 1 ppt limit for the chicken
  >recall and fish farms was simply their limit of detection,
  >not a regulatory number.
  >
  >Can anyone recommend key documents which show natural
  >background levels are lower?
  >
  >Rebecca Leighton Katers
  >Clean Water Action Council of N.E. Wisconsin
  >2220 Deckner Avenue
  >Green Bay, WI 54302
  >Phone:  414-468-4243
  >Fax:  414-468-1234
  >E-mail:  cwac@execpc.com
  >
  >
  >
  >--=====================_872660083==_
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  /
  >///////////////////////////////////////////////////////////////////////////
  /
  >///////////////////////////////////////////////////////////////////////////
  /
  >///////////////////////////////////////////////////////////////////////////
  /
  >/////////////////////////w==
  >--=====================_872660083==_--
  >
  >