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Re: Background Dioxin Levels?
If you wish, I believe my software will allow me to convert excell spread
sheets to html coded web pages, if so I will set up a page on my site where
they can be viewed online or downloaded as a saved web page. Jusyt send them
to me as attached email I can open excel sheets in my computer convert them
and publish to my site. I will then post to the list with an address where
they can be viewed.
RAymond Mills
Tradeshows Online
Developer of the Envirotrade 97 Environmental Tradeshow Online
Voice: 406-295-1316 Voice Mail and Fax: 404-685-0842
http://tradeshows-online.com mailto:rmills@tradeshows-online.com
-----Original Message-----
From: Vivien Mountford <vivmount@greener.u-net.com>
To: Multiple recipients of list <dioxin-l@essential.org>
Date: Tuesday, August 26, 1997 4:01 PM
Subject: RE: Background Dioxin Levels?
>--=====================_872660083==_
>Content-Type: text/plain; charset="us-ascii"
>
>Are Dennis's values in TEQ or not? I assume not.
>
>Lets see if this message gets through (On August 17, I tried to send some
>spreadsheets of dioxins in UK cowsmilk from near industrial sources. That
>message was rejected by the dioxin list server as being too big - if anyone
>is still interested in cowsmilk sampling, please let me know and I'll make
>time to split it down into smaller chunks).
>
>I attach Excel spreadsheet data from the 1995 UK report by H.M.
Inspectorate
>of Pollution (HMIP) on dioxin in UK soils. [1]
>Our computer is virus-checked every time it is powered on, so the attached
>file should be safe to use.
>
>This small subset of samples from survey of UK soil samples gives mean TEQ
>values
>Urban locations (Mean of 5 samples) = total I-TEQ 28.37 ng/kg (=ppt)
>Rural locations (Mean of 11 samples) = total I-TEQ 5.17 ng/kg (=ppt)
>The TEQ value for individual congeners are given in the spreadsheet.
>
>N.B. Alan Watson says the data in that report is not very representative
of
>background dioxin levels in UK soil. He says that when he has time, he will
>find and send out some better data.
>
>If you cannot read the spreadsheets and want the data instream, let me
know.
>
>As you see, this is much higher than the 2 ppt under discussion, but it is
>total TEQ per sample. This report analyses most of the samples by total
>tetra- to octa- PCDDs and PCDFs, reanalysing relatively few samples into
TEQ
>values. They gave a statistical summary of the full urban data set of 28
>samples, which showed
>
> full urban data set of 28 samples Report [1]
> mean ppt median ppt
>TCDD 70 60
>PeCDD 80 70
>HxCDD 170 180
>HpCDD 640 280
>OCDD 5500 740
>
>They didn't give a statistical summary of the rural samples, which is a
pity
>as they would better represent "background" presumably.
>
>It is interesting that in HMIP's earlier report [3] they give a summary for
>a data set of 66 samples from a 50km grid across the UK (reduced from 78
>samples by ignoring samples with value for any congener outside 2.5 std
>deviations of the mean). This would be more like background:
>
>Reduced data set of 66 UK soil samples (concentrations in ng/kg) Report
>[3] 1989
> mean ppt median ppt
>TCDD 9.4 6.0
>2,3,7,8-TCDD <0.5 <0.5
>PeCDD 6.6 4.6
>1,2,3,7,8-PeCDD <0.5 <0.5
>HxCDD 38 31
>HpCDD 66 55
>OCDD 190 140
>
>I wonder if Dennis is quoting median values, rather than mean values, as
the
>median values above match the means he quotes, from work I suspect is from
>the same co-author in the same year of 1989. I personally never got a grip
>of the difference between mean and median, (lies, damn lies and statistics
>if you ask me), but there does seem to be a difference in practise, as
above.
>
>
>The original 2ppt figure (quoted by Rebecca's FDA person) = the same
amount
>as was estimated by a Dutch government committee (in 1996) to be the
average
>dioxin intake of the Dutch population [2], so I wonder if Rebecca's FDA
>person was really talking about background level in food, after all.
>
>The Dutch report said (p14) "Most adults in the Netherlands are exposed to
>approximately 2 picogrammes of toxic equivalents of dioxin-like substances
>per kilogramme of bodyweight per day." This committee derived, from
animal
>studies, a health-based exposure limit of 1 picogramme TEQ/kg
>bodyweight/day, which they recommended instead of the WHO limit of 10 pg
>TEQ/kg bw/day. As the Dutch population generally is exposed to twice their
>recommended safe level, the committee concluded that the best way to limit
>adults and babies intake to a safe level would be to reduce the exposure of
>the whole population. I do not know whether the Dutch government has
>accepted these recommendations.
>
>[1] "Determination of polychlorinated biphenols, polychlorinated
>dibenzo-p-dioxins and polychlorinated dibenzofurans in UK soils. 2nd
>Technical Report" by E.A.Cox & C.S.Creaser. Published by the then UK
>regulators, H.M. Inspectorate of Pollution, December 1995. I ASSUME that
>the report is available from the UK Environment Agency, Rio House,
Waterside
>Drive, Aztec West, Almondsbury, Bristol, BS12 4UD, England, since HMIP
>merged to become part of this Agency.
>
>[2] "Dioxins. Polychlorinated dibenzo-p-dioxins, dibenzofurans and
>dioxin-like polychlorinated biphenols" Health Council of the Netherlands:
>Committee on Risk Evaluation of Substances/Dioxins. Rijswijk: Health
>Council of the Netherlands, 1996; Publication no. 1996/10E
>
>[3] "Determination of polychlorinated biphenols, polychlorinated
>dibenzo-p-dioxins and polychlorinated dibenzofurans in UK soils." H.M.
>Inspectorate of Pollution, 1989.
>
>Viv Mountford
>
>At 12:16 26/08/97 -0400, Catalano, Dennis wrote:
>>This 2 -3 ppt range is a bit low actually from some references I have
>>seen. A study of soils in the UK had mean values of background of 6ppt
>>for TCDD up to 143ppt for OCDD. The furans ranged from 16ppt for TCDF
>>to 32 ppt for HxCDF. This data can be found in:
>>
>>Survey of Background Levels of PCDDs & PCDFs in UK Soils, Chemosphere,
>>Vol 18 Nos 1-6 pp 767-776 1989.
>>
>>Some papers I have read find similar levels in the US. I am sorry, but
>>I do not have references to those at my fingertips.
>>
>>Dennis Catalano
>> ----------
>From: Rebecca Leighton Katers
>To: Multiple recipients of list
>Subject: Background Dioxin Levels?
>Date: Tuesday, August 26, 1997 8:11AM
>
>I was just told by an FDA policy person that
>recent information shows that dioxin background
>levels range from 2 to 3 ppt.
>
>This seemed awfully high to me, so I questioned
>him and asked if he meant background
>in the food supply or natural background in the
>soil --- and he said natural background in soil.
>
>He said that the 1 ppt limit for the chicken
>recall and fish farms was simply their limit of detection,
>not a regulatory number.
>
>Can anyone recommend key documents which show natural
>background levels are lower?
>
>Rebecca Leighton Katers
>Clean Water Action Council of N.E. Wisconsin
>2220 Deckner Avenue
>Green Bay, WI 54302
>Phone: 414-468-4243
>Fax: 414-468-1234
>E-mail: cwac@execpc.com
>
>
>
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/
>///////////////////////////////////////////////////////////////////////////
/
>///////////////////////////////////////////////////////////////////////////
/
>///////////////////////////////////////////////////////////////////////////
/
>/////////////////////////w==
>--=====================_872660083==_--
>
>