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Tire burning
I am working with a group of citizens who are trying to stop a
co-generation plant from switching to a fuel mix that would be 50%
tire chips. Any information anyone has as to the adverse
environmental impacts of tire-to-energy plants would be helpful. I
am, however, particularly interested in dioxin/furan emissions. The
IARC monograph on rubber lists over a hundred pages of the chemicals
that are commonly found in rubber, many of which are organochlorines,
including pentachlorophenol. Tires thus appear to provide a rich source of carbon, hydrogen, and
chlorine. Since these tires are being burned, heat is obviously
present. Industry -- via chlorophiles -- informs us that the
presence of certain metallic catalysts has a large bearing on the
amount of dioxin that is produced. Tires contain steel belts, which
are alloys of iron, carbon, molybendum, and probably chromium. The
cogeneration plant is already emitting lead, arsenic, and zinc. To
what extent do these metals act as catalysts for the formation of
dioxin/furans? Can anyone give me journal cites and/or the names of
experts? What are the records of other tire-to-energy facilities?
The present plant burns wood waste. How does the temperature in such
a plant compare to the higher temperatures the chlorophiles say
destroy most dioxin-like compounds? Is there any validity to
comparing wood/tire-to-energy plants with cement kilns? To municipal
or medical waste incinerators? Any and all information would be
appreciated. Send it to the list or to my mailbox -- pjc@igc.apc.org